Constraining East Asia ammonia emissions through satellite observations and iterative Finite Difference Mass Balance (iFDMB) and investigating its impact on inorganic fine particulate matter.

Uncertainty in ammonia (NH3) emissions causes the inaccuracy of fine particulate matter simulations, which is associated with human health. To address this uncertainty, in this work, we employ the iterative finite difference mass balance (iFDMB) technique to revise NH3 emissions over East Asia using the Cross-track Infrared Sounder (CRIS) satellite for July, August, and September 2019. Compared to the emissions, the revised NH3 emissions show an increase in China, particularly in the North China Plain (NCP) region, corresponding to agricultural land use in July, August, and September and a decrease in South Korea in September. The enhancement in NH3 emissions resulted in a remarkable increase in concentrations of NH3 by 5 ppb. in July and September, there is an increase in ammonium (NH4+) and nitrate (NO3-) concentrations by 5 µg/m3, particularly in the NCP region, while in August, both NH4+ and NO3- concentrations exhibit a decrease. For sulfate (SO42-), in August and September, the concentrations decreased over most regions of China and Taiwan, as a result of the production of ammonium sulfate; increased concentrations of SO42-, however, were simulated over South Korea, Japan, and the southern region of Chengdu, caused by higher relative humidity (RH). In contrast, during the month of July, our simulations showed an increase in SO42- concentrations over most regions of China. To gain a more comprehensive understanding, we defined a sulfur conversion ratio ( [Formula: see text] ), which explains how changes in sulfur in the gas phase affect changes in sulfate concentrations. A subsequent sensitivity analysis performed in this study indicated the same relationship between changes in ammonia and its effect on inorganic fine particulate matter (PM2.5). This study highlights the challenge of controlling and managing inorganic PM2.5 and indicates that reducing the emissions of air pollutants do not necessarily lead to a reduction in their concentrations.

Air quality and health co-benefits of vehicle electrification and emission controls in the most populated United States urban hubs: Insights from New York, Los Angeles, Chicago, and Houston.

Transitioning to electric vehicles (EVs) is a prominent strategy for reducing greenhouse gas emissions. However, given the complexity of atmospheric chemistry, the nuanced implications on air quality are yet to be fully understood. Our study delved into changes in PM2.5, ozone, and their associated precursors in major US urban areas, considering various electrification and mitigation scenarios. In the full electrification (FullE) scenario, PM2.5 reduction peaked at values between 0.34 and 2.29 µg.m-3 across distinct regions. Yet, certain areas in eastern Los Angeles exhibited a surprising uptick in PM2.5, reaching as much as 0.67 µg.m-3. This phenomenon was linked to a surge in secondary organic aerosols (SOAs), resulting from shifting NOx/VOCs (volatile organic compounds) dynamics and a spike in hydroxyl radical (OH) concentrations. The FullE scenario ushered in marked reductions in both NOx and maximum daily average 8-h (MDA8) ozone concentrations, with maximum levels ranging from 14.00 to 32.34 ppb and 2.58-9.58 ppb, respectively. However, certain instances revealed growths in MDA8 ozone concentrations, underscoring the intricacies of air quality management. From a health perspective, in the FullE scenario, New York, Chicago, and Houston stand to potentially avert 796, 328, and 157 premature deaths/month, respectively. Los Angeles could prevent 104 premature deaths/month in the HighE-BL scenario, representing a 29 % EV share for light-duty vehicles. However, the FullE scenario led to a rise in mortality in Los Angeles due to increased PM2.5 and MDA8 ozone levels. Economically, the FullE scenario projects health benefits amounting to 51-249 million $/day for New York, Chicago, and Houston. In contrast, Los Angeles may face economic downturns of up to 18 million $/day. In conclusion, while EV integration has the potential to improve urban air quality, offering substantial health and economic advantages, challenges persist. Our results emphasize the pivotal role of VOCs management, providing policymakers with insights for adaptable and efficient measures.

Changes in the ozone chemical regime over the contiguous United States inferred by the inversion of NOx and VOC emissions using satellite observation.

To investigate changes in the ozone (O3) chemical production regime over the contiguous United States (CONUS) with accurate knowledge of concentrations of its precursors, we applied an inverse modeling technique with Ozone Monitoring Instrument (OMI) tropospheric nitrogen dioxide (NO2) and total formaldehyde (HCHO) retrieval products in the summers of 2011, 2014, and 2017, years in which United States National Emission Inventory were based. The inclusion of dynamic chemical lateral boundary conditions and lightning-induced nitric oxide emissions significantly account for the contribution of background sources in the free troposphere. Satellite-constrained nitrogen oxide (NOx) and non-methane volatile organic compounds (NMVOCs) emissions mitigate the discrepancy between satellite and modeled columns: the inversion suggested 2.33-2.84 (1.07-1.34) times higher NOx over the CONUS (over urban regions) and 0.28-0.81 times fewer NMVOCs emissions over the southeastern United States. The model-derived HCHO/NO2 column ratio shows gradual spatial changes in the O3 production regime near urban cores relative to previously defined threshold values representing NOx and VOC sensitive conditions. We also found apparent shifts from the NOx-saturated regime to the transition regime (or the transition regime to the NOx-limited regime) over the major cities in the western United States. In contrast, rural areas, especially in the east-southeastern United States, exhibit a decreased HCHO/NO2 column ratio by -1.30 ± 1.71 with a reduction in HCHO column primarily driven by meteorology, becoming sensitive to VOC emissions. Results show that incorporating satellite observations into numerical modeling could help policymakers implement appropriate emission control policies for O3 pollution.